DNR TV on Learning C#
Carl Franklin and I got together and did an intro to C# for VB.NET developers last month.
The first version is up here: http://www.dnrtv.com/
Or, watch the silverlight version here: http://perseus.franklins.net/dnrtv/0096/silverlight/video.html
This discussion is somewhat introductory, it should be approachable for a beginning C# developer. Carl is a great interviewer. Those who know me know that I'm not particularly fluent in VB.NET. Carl does a great job of leading me toward topics that will make this discussion clear for the VB.NET developer who is learning C#.